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Niman, John W.; Kamerin, Benjamin S.; Kresin, Vitaly V.; Krohn, Jan; Signorell, Ruth; Halonen, Roope; Hansen, Klavs (, Physical Chemistry Chemical Physics)Abundance spectra of (CO 2 ) N clusters up to N ≈ 500 acquired under a wide range of adiabatic expansion conditions are analyzed within the evaporative ensemble framework. The analysis reveals that the cluster stability functions display a strikingly universal pattern for all expansion conditions. These patterns reflect the inherent properties of individual clusters. From this analysis the size-dependent cluster binding energies are determined, shell and subshell closing sizes are identified, and cuboctahedral packing ordering for sizes above N ≈ 130 is confirmed. It is demonstrated that a few percent variation in the dissociation energies translates into significant abundance variations, especially for the larger clusters.more » « less
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Adams, Christopher L.; Hansen, Klavs; Weber, J. Mathias (, The Journal of Physical Chemistry A)
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